Petroleum Reservoir Engineering Physical Properties by Amyx, Bass, Whiting,

By Amyx, Bass, Whiting,

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This illustration shows two wells: n n Well 1 penetrates the gas cap with a recorded gas pressure of pg and a measured gas density of ρg. Well 2 penetrates the oil zone with a recorded oil pressure of po and oil density of ρo. 40 Pressure gradient vs. depth.

Outside the phase envelope, only one phase can exist. 7 Pressure-volume diagram for a binary system. 4 24 CHAPTER 1 Fundamentals of Hydrocarbon Phase Behavior If the bubble point pressure and dew point pressure for the various isotherms on a p-V diagram are plotted as a function of temperature, a p-T diagram similar to that shown in Fig. 8 is obtained. Fig. 8 indicates that the pressure-temperature relationships no longer can be represented by a simple vapor pressure curve, as in the case of a single-component system, but take on the form illustrated in the figure by the phase envelope ACB.

Critical point: The critical point for a multicomponent mixture is referred to as the state of pressure and temperature at which all intensive properties of the gas and liquid phases are equal (point C). At the critical point, the corresponding pressure and temperature are called the critical pressure, pc, and critical temperature, Tc, of the mixture. Phase envelope (two-phase region): The region enclosed by the bubble point curve and the dew point curve (line BCA), where gas and liquid coexist in equilibrium, is identified as the phase envelope of the hydrocarbon system.

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